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KMID : 1059519880320030243
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Journal of the Korean Chemical Society
1988 Volume.32 No. 3 p.243 ~ p.248
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A Study on the Hypersensitive Transitions of Nd(III), Ho(III) and Er(III) Complexes in Aqueous Solution
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Yun Sock-Sung
Choi Ki-Young
Park Kyoung-Kyun
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Abstract
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The hypersensitive f→f transitions of Nd(Ⅲ), Ho(Ⅲ), and Er(Ⅲ) have been studied for some lanthanide complexes in aqueous solution. Based on the linear correlation between the oscillator strength of the transition and the basicity(pKa) of the ligand, the covalency in the metal-ligand bonding is discussed for lanthanide anthranilate, pyrazine-2-carboxylate, and pyruvate.
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KEYWORD
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